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Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI/CuII complexes

献明 张;明良 童;小明 陈

China Association for Science and Technology

发表时间:2002-3-15

期 刊:Angewandte Chemie - International Edition

语 言:English

U R L: http://www.scopus.com/inward/record.url?scp=0037087715&partnerID=8YFLogxK

摘要

Structural evidence for the Gillard mechanism of covalent hydrates is provided by two mixed-valence CuI/CuII complexes containing 2,2′-bipyridine (see picture) or 1,10-phenanthroline ligands, in which a hydroxy group is added to a carbon atom adjacent to a nitrogen atom. These complexes are synthesized by hydrothermal treatment of Cu(NO3)2, the respective N,N ligand, and terephthalic acid.

关键词

Copper
Hydroxylation
Mixed-valent compounds
N ligands
Reaction mechanisms

相关科学

化学工程
催化
化学

文献指纹

化合物

Hydroxylation

Atoms

terephthalic acid

1,10-phenanthroline

Ligands

Hydrates

Carbon

Nitrogen

工程与材料科学

Hydroxylation

Ligands

Atoms

Hydrates

Nitrogen

Acids

Carbon

被引量

期刊度量

Scopus度量

年份 CiteScore SJR SNIP
1996
1997
1998
1999 3.529 2.147
2000 3.852 2.169
2001 3.788 2.139
2002 3.744 2.134
2003 3.559 2.099
2004 4.247 2.173
2005 4.797 2.286
2006 4.868 2.271
2007 4.528 1.923
2008 5.589 2.203
2009 5.571 2.249
2010 5.921 2.291
2011 16.7 6.063 2.354
2012 16.5 6.407 2.329
2013 17 5.702 2.2
2014 18.3 5.811 2.302
2015 19 5.888 2.229
2016 18.7 5.954 2.185
2017 19.7 6.155 2.195
2018 20.2 5.478 2.148
2019 20.8 5.438 2.254
2020 19.5

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